Here is my approach.. and its not always a good one because airguns and pb'ers differ not only in the propellant but how much force the propellants make. A 357 magnum produces like 44000 psi in the chamber, an air rifle is sending 2-3000 psi behind the bullet. So I think that PB bullets form to the barrel better due to the extreme force behind them when the round goes off, I do not believe the same thing happens with airgun projectiles and that is why you'll find a lot of big bore airgun guys actually oversizing their rounds to the bore of their barrel so they make good contact with the rifling.
I think thats why my approach isn't always the best, but I am just thinking aloud here and trying to help so forgive my ramblings because I haven't been able pin point what works in some and why it doesn't work in others.
First thing you need to know is the rifles barrel twist rate, take that information and right it down, then you need to know the diameter of the barrel, this is done by slugging the barrel, or you can ask around and get a ball park. Once barrel specs are acquired, look at the round you are choosing, match the diameter of the round to the barrel, then get the BC of the round (some are published but bc changes in flight as well.... this is still something I have yet to fully understand)....
Take that data, and plug it into a stability factor calculator and then plug your info into ballistics calculator to see what will work for you.
I really do not like the idea of buying this ammo, that ammo, this ammo, that ammo, till you find what one works, you could literally spend 500 dollars in ammo before finding the right one.
Here are my two favorite calculators
First one is a stability factor calculator
If the stability factor calculator comes up with a poor SF its probably not going to do well...
Our newly updated Twist Rate Stability Calculator not only tells you what your SG is, but it also lets you know if you are reaching your optimized BC.
bergerbullets.com
Second one is a ballistics calculator